氧钒(IV)配合物,oxovanadium(IV) complexes
1)oxovanadium(IV) complexes氧钒(IV)配合物
2)Vanadium complex钒氧配合物
1.The new vanadium complexes VO(acac)(HB(pz)3)(1) and VO(acac) (HB(3,5-Me2pz)3) ·CH3CN(2) with poly-pyrazolylborate as the ligand were synthesized.合成了2种以聚类吡唑硼酸盐配体的钒氧配合物,VO(acac)(HB(pz)3)(1)和VO(acac)-(HB(3,5- Me2pz)3)·CH3CN(2)。
英文短句/例句
1.Design、Synthesis and Characterization of Oxovanadium Complex Containing Poly (Pyrazolyl) Borate;含有聚吡唑硼酸盐配体的钒氧配合物的设计、合成与表征
2.Effects of a New Oxovanadium Complex on the Renal Function and Insulin Receptor Signal Transduction of Diabetic Mice新型钒氧配合物对糖尿病小鼠肾脏功能及胰岛素受体信号转导的影响
3.Investigation on the Radical Scavenging Effect of Coordination Complex of Quercetin with Vanadium;槲皮素及其氧钒配合物抗氧化性研究
4.The Studies on the Biological Activity and Quantization Calculation of the Oxovanadium Complexes;氧钒配合物的生物活性研究及其量化计算
5.Hypoglycemic Effects of Bis (α-furancarboxylato) Oxovanadium (IV) in Alloxan-diabetic Mice and Its Preliminary Mechanisms;新型钒配合物双（α-呋喃甲酸）氧钒的降糖作用及机理分析
6.Synthesis and Crystal Structure of [VO_2(Sal)(Phen)]·H_2O水杨醛邻菲咯啉氧钒配合物的合成和晶体结构
7.Synthesis,Structure and Quantum Chemistry Calculation of Scorpionate Oxovanadium Complexes with Benzoate蝎型钒氧苯甲酸配合物的合成、结构及量化计算
8.NMR Studies on Interactions between Diperoxovanadate and Small Organic Molecules;过氧钒配合物与有机小分子相互作用的NMR研究
9.Inhibitory Activities of Some Oxovanadium Complexes with N-Heterocyclic Ligands against PTP1B/ALP含氮杂环氧钒配合物对PTP1B和ALP的抑制活性研究
10.Hydrothermal Synthesis of Decavanadium Oxide Complex with 1,10-phenanthroline;以1,10-邻菲罗啉为配体的钒氧酸盐配合物的水热合成
11.Synthesis and characterization of ternary oxovanadium(Ⅳ) complexes with polypyridyl and salicylaldehyde alanine Schiff base水杨醛缩丙氨酸Schiff碱氧钒-多吡啶三元混配配合物的合成及表征
12.Studies on Scorpionates Oxovanadium-amino-acid Complex with Potential Biological Activities;具有潜在生物活性的蝎型氧钒氨基酸配合物的研究
13.Synthesis, Characterization and Inhibitory Activity in PTP1B of Oxovanadium Compounds with Benzimidazole Ligands苯并咪唑类氧钒配合物的合成、表征及对PTP1B抑制活性研究
14.The Study of the Modification of Vanadium-containing Polyoxometalates Using Transition-metal Complexes;含钒多金属氧酸盐的过渡金属配合物修饰化研究
15.Polypyridyl and Amino Acid Schiff Base Oxovanadium Compounds with Primary Study of PTP1B Inhibitory Acitivity水杨醛缩氨基酸希夫碱氧钒—多吡啶三元配合物抑制PTP1B的研究
16.NMR Studies on Interactions between Diperoxovanadate and 1-Ethyl-1H-Imidazole双过氧钒配合物与N-乙基咪唑相互作用的NMR研究
17.Interactions between Diperoxovanadate and 2-Methyl-imidazole Studied by NMR Spectroscopy双过氧钒配合物与2-甲基咪唑相互作用的NMR研究(英文)
18.Synthesis,Structure and Biological Activity of Vanadium Complexes Containing Acylhydrazone Ligands钒酰腙配合物的合成、结构及生物活性
相关短句/例句
Vanadium complex钒氧配合物
1.The new vanadium complexes VO(acac)(HB(pz)3)(1) and VO(acac) (HB(3,5-Me2pz)3) ·CH3CN(2) with poly-pyrazolylborate as the ligand were synthesized.合成了2种以聚类吡唑硼酸盐配体的钒氧配合物,VO(acac)(HB(pz)3)(1)和VO(acac)-(HB(3,5- Me2pz)3)·CH3CN(2)。
3)oxovanadium complex氧钒配合物
1.The inhibitory activities against PTP1B and alkaline phosphatase (ALP) byoxovanadium complexes with 2,2\"-biimidazole (L1), 2,2\"-bipyridine (L2) and 1,10-phenanthroline (L3) have been investigated in vitro.研究了三种含氮平面杂环螯合配体2,2\"-联咪唑(L1),2,2\"-联吡啶(L2),1,10-邻菲咯啉(L3)的氧钒配合物对PTP1B以及碱性磷酸酶(alkaline phosphatase,ALP)的体外抑制作用。
4)diperoxovanadate双过氧钒配合物
1.NMR Studies on Interactions between Diperoxovanadate and 1-Ethyl-1H-Imidazole双过氧钒配合物与N-乙基咪唑相互作用的NMR研究
2.To understand the effects of organic ligands of thediperoxovanadate complexes on the reaction equilibrium,the interactions between a series ofdiperoxovanadate complexes [OV(O2)2LL"]n- [n=1～3;LL"=oxalate,abbr.15mol/L NaCl溶液),应用多核(1H,13C和51V)多维(COSY)NMR以及变温技术等谱学方法研究双过氧钒配合物[OV(O2)2LL"]n-[n=1～3,LL"=oxalate(缩写为oxa)、picolinate(缩写为pic)、bipyridine(缩写为bipy)和1,10-phenanthroline(缩写为phen),与它们配位的含钒物种分别缩写为bpV(oxa),bpV(pic),bpV(bipy)和bpV(phen)]与N-甲基咪唑(缩写为N-Me-Im)的相互作用,实验结果表明N-Me-Im与4种双过氧钒配合物的反应活性从强到弱的顺序为:bpV(oxa)>bpV(pic)>bpV(bipy)>bpV(phen)。
3.To understand the substituting effects of organic ligands on the reaction equilibrium, the interac- tions betweendiperoxovanadate complex [OV(O2)2(D2O)]-/[OV(O2)2(HOD)]- and a series of N-substituted picolinamide ligands in solution were explored using multinuclear (1H, 13C, and 51V) magnetic resonance, COSY, DOSY, and variable temperature NMR in 0.15mol/LNaCl溶液),应用多核(1H,13C和51V)多维(COSY和DOSY)NMR以及变温技术等谱学方法研究双过氧钒配合物[OV(O2)2(D2O)]-/[OV(O2)2(HOD)]-与N-取代皮考啉酰胺的相互作用。
5)Diperoxovanadate complex双过氧钒配合物
1.The interaction between diperoxovanadate complex [OV(O2)2(D2O)]-/[OV(O2)2(HOD)]- (abbr.15mol/LNaCl溶液),应用多核(1H和51V)多维(DOSY)NMR以及变温技术等谱学方法研究双过氧钒配合物[OV(O2)(2D2O)]-/[OV(O2)(2HOD)](-简写为bpV)与4,4"-联吡啶(简写为bipy)的相互作用。
6)vanadium(V)-peroxo complexes过氧化钒配合物
1.Singlet oxygen from the photolysis of vanadium(V)-peroxo complexes may be considered as the main contributing reactive oxygen species to the oxidation of thymine base.胸腺嘧啶残基与过氧化钒配合物的光照射反应,由过氧化钒配合物光分解所产生的单线态氧使胸腺嘧啶碱基发生了光氧化反应,可能的反应产物通过核磁共振氢谱进行了测定。
延伸阅读
外轨配合物和内轨配合物根据L.C.鲍林的价键理论,具有八面体结构并有4个未成对电子的、顺磁性的[CoF6]3-,或有5个未成对电子的、顺磁性的[Fe(H2O)6]3+,其配位成键杂化轨道为4s4p34d2，所用d 轨道与s和p轨道是属于同一主能级的。这类具有nsnp3nd2形式的配合物(见配位化合物), 因为使用了外层的d轨道,所以叫做外轨配合物。两种配合物的杂化成键轨道分别如图所示。对于具有八面体结构且所有电子都是成对的、抗磁性的[Co(NH3) 6]3+， 或具有1个未成对电子的、 顺磁性的[Fe(CN)6]3-,其成键杂化轨道为3d24s4p3,使用了比s和p轨道低一级主能级层中的d轨道。这类具有(n-1)d2nsnp3型式的配合物,由于使用了内层的d轨道，所以叫做内轨配合物。在四配位体系中，具有四面体结构且有两个未成对电子的顺磁性的[NiCl4] 2-,其成键杂化轨道为4s4p3,属外轨配合物。而所有电子都成对的、抗磁性的[Ni(CN)4]2-，其成键杂化轨道为3d4s4p2,是平面正方形结构，属内轨配合物。两种配合物的杂化成键轨道如图所示。
